adipic acid hazards

( None of the chemicals in this product have a TPQ. h 0 -1 TD 602.774 180.321 l 602.774 682.2 l (atmosphere by reaction with hot chemically-produced hydroxyl radicals; t\ he half-life for this reaction in air is )Tj W* n q EMC 0 -1.201 TD 11.533 581.229 l (OSHA Vacated PELs:)Tj 0.949 0.945 0.935 rg /Artifact <>BDC q 454.771 225.195 l 0 -1.201 TD /T1_0 1 Tf 9.226 368.703 593.548 26.141 re 0 18 612 756 re 10.764 178.784 m ... ADIPIC ACID; 2 OCTANOL (CAPRYL ALCOHOL) 2 ETHYLHEXANOIC ACID (2EH ACID) 2 ETHYL HEXYL ALCOHOL (2-ETHYLHEXANOL) BEHENYL ALCOHOL 70 (C2270) 601.236 414.985 l 9.226 64.856 l 7.688 440.723 l 363.104 465.577 m 0.801 0.801 0.801 rg 0 18 612 756 re (capable of creating a dust explosion. BT 0 -1.201 TD 601.236 89.459 m ( 0.073 mm Hg @ 18.5 deg C )Tj 9.226 433.222 l Adipic acid These corrosion data are mainly based on results of general corrosion laboratory tests , carried out with pure chemicals and water solutions nearly saturated with air (the corrosion rate can be quite different if the solution is free from oxygen). View information & documentation regarding Adipic acid, including CAS, MSDS & more. )Tj h /TT1 1 Tf h 601.236 630.922 l 0 i 0 18 612 756 re f /Artifact <>BDC 7.688 396.899 m 0 18 612 756 re 600.467 581.229 l /Article <>BDC /TT0 1 Tf 8.457 479.032 l EMC f Particulate-phase adipic acid may be phy\ sically removed from the air. 7.688 440.723 m /Artifact <>BDC /TT1 1 Tf f 9.226 559.198 593.548 26.141 re 7.688 63.319 l 0 -1.201 TD Clinical examination of workers\ engaged in adipic acid )Tj q 600.467 754.911 l f including trade names and synonyms. 9.9358 0 0 9.9358 7.6884 438.3586 Tm W* n 601.236 370.241 l /TT0 1 Tf 604.312 92.535 m 8.457 468.402 m 377.41 454.947 l f (https://fscimage.fishersci.com/msds/00390.htm \(1 of 5\)7/20/2007 8:34:5\ 8 AM)Tj (US DOT)Tj (rposes. Almost 90 percent of adipic acid produced is used in the production of nylon 66. q W* n 601.236 583.801 m 603.543 411.758 l h Q (Potential Health Effects)Tj /Artifact <>BDC q 363.104 452.123 l (Chemical Name)Tj 600.467 559.702 l /TT1 1 Tf 604.312 490.565 l q h 0 0 0 rg (Vapor Pressure:)Tj W* n 34.962 0 Td f 9.9358 0 0 9.9358 7.6884 391.9206 Tm 603.543 441.492 l (Specific Gravity/Density:)Tj f 377.41 454.947 m 10.764 460.43 l 604.312 181.859 l A wide variety of products is possible. f )Tj 600.467 504.478 l /TT1 1 Tf 9.226 322.817 593.548 26.141 re f )Tj 156.46 237.881 l f h It is insoluble in water. 0 0 0 rg Their reaction with carbonates and bicarbonates generates a harmless gas (carbon dioxide) but still heat. (adequate ventilation. 0000000399 00000 n Conventionally it was manufactured from petrochemicals but in recent days it can be synthesized from renewable substrates by means of biological methods. EMC 0 18 612 756 re 9.9358 0 0 9.9358 7.6884 302.2832 Tm f 376.641 442.261 l (For International CHEMTREC assistance, call:)Tj T* (CAS# 124-04-9 is listed as a Hazardous Substance under the CWA. f 0 18 612 756 re (Adipic acid)Tj 8.457 411.758 l /WebCaptureFN <>BDC W* n 377.41 441.492 l f 7.688 152.643 l W* n 0000056699 00000 n W* n Avoid creating a dust cloud in handling, transfer and clean up. EMC 122.292 442.261 l /TT0 1 Tf f 0000057205 00000 n 11.533 630.153 l Safety Data Sheet. h Q 0 18 612 756 re /TT1 1 Tf /Artifact <>BDC 9.226 368.703 l 0 -1.201 TD (Inhalation:)Tj (gastrointestinal tract and in the mucosa of the upper respiratory tract.\ )Tj f /TT1 1 Tf T* ( )Tj 8.457 454.947 m h 454.771 252.105 m 0 -1.1 TD (guidelines for the classification determination are listed in 40 CFR Par\ ts 261.3. (SARA Section 302 Extremely Hazardous Substances)Tj 604.312 224.426 l 604.312 680.662 l /TT0 1 Tf 122.666 425.213 l Adipic acid is a substance used for the preparation of nylon, polyurethanes, and other products of commercial interest. 483.757 442.261 l Facilities storing or\ utilizing this material should be equipped )Tj (Other Studies:)Tj 0 -1.2 TD 0 Tc 0 Tw 0 Ts 100 Tz 0 Tr 6.9196 0 0 6.9196 18 781.7488 Tm ( )Tj /TT1 1 Tf 6.9196 0 0 6.9196 18 8.7488 Tm ET Q T* 0 -1.2 TD 484.526 441.492 l q /TT1 1 Tf f Store in a cool, dry, well-ventilated area away from incompat\ ible substances. h h The waste … Observe all recommended safety precautions until container is cleaned, reconditioned, or destroyed. 602.774 442.261 l 8.457 468.402 m Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9351 ( )Tj 378.179 455.716 l ( )Tj f f 156.46 251.336 l ( )Tj /TT1 1 Tf 157.229 238.65 l safety hazards of Adipic Acid to potentially exposed workers. 0.949 0.945 0.935 rg ( )Tj 0.949 0.945 0.935 rg 7.688 758.755 m 485.294 455.716 l Get medical aid. h 600.467 482.951 l 7.688 410.99 m 0.457 0.449 0.431 rg 603.543 225.195 l f f 602.774 452.892 l 9.226 322.817 l h 9.226 90.997 l 7.688 557.661 m 11.533 706.034 l 604.312 367.165 l Q 454.771 252.105 m 603.543 465.577 l W* n It is used to make plastics and foams and for other uses. 603.543 441.492 l (Reproductive Effects:)Tj 10.764 607.857 l This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). 485.294 442.261 l ( Causes eye irritation. 0 -1.201 TD ET /TT0 1 Tf f ( )Tj Hazards identified by OECD/ICCA high production volume chemicals program in 2004: "Adipic acid was orally administered to humans to investigate compound excretion. 0.753 0.753 0.753 rg )Tj f Hazard statements were adapted to improve readability and may not correspond textually to the hazard statements codes description in the European Union Specific Hazard Statements ... Adipic acid ,CAS N°124-04-9, Radici Chimica S.p.A. (none listed )Tj ( Oral, rat: LD50 = >11 gm/kg; )Tj (Clean Water Act:)Tj ( 3.2 \(0.1% soln\) )Tj 10.764 516.706 m /T1_0 1 Tf 16/05/2017 EN (English) 3/5 8.2. (Notes to Physician:)Tj 0 -1.201 TD 8.457 468.402 l 0.949 0.945 0.935 rg f 0 18 612 756 re f (Extinguishing Media:)Tj ( CAS# 124-04-9 can be found on the following state right to know lis\ ts: California, New Jersey, Pennsylvania, )Tj 9.226 398.437 l 8.457 425.213 l 306 252.105 l 8.457 425.213 m f h 0 -1.201 TD 9.226 458.892 593.548 26.141 re /Artifact <>BDC ( 201-796-7100 )Tj f 7.688 709.878 m ( no )Tj f /T1_0 1 Tf /TT0 1 Tf Q 0.801 0.801 0.801 rg f 363.104 479.032 m 122.666 452.123 m 604.312 460.901 l /TT1 1 Tf 0 0 0 rg 0 18 612 756 re /TT0 1 Tf /TT1 1 Tf )Tj 10.764 683.738 m f Emptied container retains product residue. 485.294 467.633 l (Chronic:)Tj 7.688 396.382 m /WebCaptureFN <>BDC /TT0 1 Tf (USCG, 1999). W* n 601.236 560.736 l f ( )Tj f /TT1 1 Tf h (Appearance:)Tj 601.236 483.495 l 378.179 442.261 l T* 454.771 238.65 l 601.236 581.998 m h 601.236 457.825 l /TT1 1 Tf (with an eyewash facility and a safety shower. 0.753 0.753 0.753 rg 604.312 604.781 l 0 -1.201 TD )Tj 0 0 0 rg 601.236 460.43 l Figure 1. Q W* n Minimum explosible concentration in air (dust): 10-15 mg/L. 602.774 583.536 l 11.533 435.529 l 603.543 252.105 l EMC 10.764 155.718 l 7.688 460.901 m f (pressure. 0 -1.2 TD h Such reactions occur in principle for solid carboxylic acids as well, but are slow if the solid acid remains dry. ( odorless )Tj In no )Tj 0 -1.2 TD ET f W* n 8.457 438.668 m 483.757 455.716 l /Artifact <>BDC Office of Response and Restoration, 0.313 0.313 0.313 rg 9.226 455.716 111.529 11.917 re /TT0 1 Tf Immediate steps should be taken to limit its spread to the environment. (Vapor Density:)Tj f 601.236 155.718 l 8.457 452.123 m Even "insoluble" carboxylic acids may absorb enough water from the air and dissolve sufficiently in it to corrode or dissolve iron, steel, and aluminum parts and containers. 17.2 0 Td 363.104 465.577 m 0 -1.1 TD (MSDS Creation Date:)Tj /TT1 1 Tf ( 196 deg C \( 384.80 deg F\) )Tj (Chemical Test Rules)Tj -49.345 -1.556 Td f /Artifact <>BDC 362.335 478.263 l 7.688 479.106 l f 454.003 239.419 l Adipic acid Safety Data Sheet Safety Data Sheet in accordance with regulation (EC) No 1907/2006, as amended. ( No data available. ET 0 18 612 756 re The industrial synthesis of adipic acid uses nitric acid oxidation of a mixture of cyclohexanone and cyclohexanol termed “KA oil” (ketone and alcohol-oil). )Tj h h EMC /TT1 1 Tf 602.774 225.964 l 157.229 252.105 m Acrobat Web Capture 7.0 ( Carbon monoxide, carbon dioxide. Q f 601.236 399.975 l /Artifact <>BDC (The information above is believed to be accurate and represents the best\ information currently available to us. 157.997 251.336 l f 484.526 454.947 m /TT1 1 Tf 0 18 612 756 re 363.104 479.032 m Adipic Acid Dihydrazide 1071-93-8 100% Section 3 – Hazards Identification Emergency Overview OSHA Hazards No known OSHA hazards HMIS Classification Health Hazard: 0 Flammability: 1 Physical hazards: 0 NFPA Rating Health Hazard: 0 Fire: 1 Reactivity Hazard: 0 Potential Health Effects Inhalation … 604.312 586.877 m 0000000016 00000 n f 0 18 612 756 re ( )Tj /TT1 1 Tf EMC ( )Tj ( )Tj (breathing dust. 0.801 0.801 0.801 rg 602.774 368.703 l EMC 11.533 88.69 l /TT1 1 Tf )Tj Q 485.294 455.716 l 10.764 324.354 l EMC 8.457 252.105 m 0 18 612 756 re Nearly all commercial adipic acid is produced from cyclohexane. 123.434 452.892 l 0000000609 00000 n f 604.312 173.76 m T* /TT1 1 Tf ( )Tj 0 -1.201 TD 601.236 483.495 m Crystalline adipic acid should be stored … /TT0 1 Tf Q T* (airborne levels below recommended exposure limits. (https://fscimage.fishersci.com/msds/00390.htm)Tj f 602.774 413.448 l f EMC (S79883, A44-500 )Tj h Carboxylic acids with six or fewer carbon atoms are freely or moderately soluble in water; those with more than six carbons are slightly soluble in water. h (\(approved or equivalent\), and full protective gear. -30.591 -2.577 Td 484.526 441.492 l 13.8392 0 0 13.8392 212.2048 754.9995 Tm 9.226 518.243 l 600.467 392.537 l h 122.666 465.577 m (OSHA:)Tj 10.764 706.803 m 604.312 152.643 l /TT0 1 Tf 0 18 612 756 re 377.41 468.402 m ( No data available. W* n h EMC f h 7.688 173.76 m It is also used in the production of polyurethanes, resins, plasticizers, adhesives, lubricants and in food and pharmaceutical industries. f q 454.771 238.65 m h 0 -1.2 TD h f 7.688 441.126 m h q EMC (Freezing/Melting Point:)Tj /Artifact <>BDC 377.41 441.492 m (Section 3 - Hazards Identification )Tj f h 0.949 0.945 0.935 rg /Artifact <>BDC 0 -1.2 TD )Tj )Tj 602.774 348.957 l The available safety test data were insufficient to judge the safety of use of Adipic Acid Dihydrazide in cosmetic products. f 157.997 225.964 l 600.467 169.916 l h Like other acids, carboxylic acids may initiate polymerization reactions; like other acids, they often catalyze (increase the rate of) chemical reactions. )Tj W* n 363.873 466.346 l 601.236 706.803 m /TT1 1 Tf f 10.7638 0 0 10.7638 7.6884 548.7429 Tm 9.9358 0 0 9.9358 7.6884 216.1945 Tm f 484.526 454.947 l 7.688 709.878 m f 603.543 252.105 l It is insoluble in water. Adipic Acid (ADIPC) Safety Data Sheet According to the occupational safety and health (classification, labelling, and safety data sheet of hazardous chemicals) Regulation 2013 06/04/2017 EN (English US) 2/7 Name Product identifier % Classification according to the United Nations GHS (Rev. /TT0 1 Tf 601.236 683.738 l (Incompatibilities with Other Materials:)Tj /TT1 1 Tf Q 7.688 519.781 m h 305.231 251.336 l 604.312 709.878 m Q 9.226 464.809 l (Eyes:)Tj h <<290FCF00353D7E4DBCD557A9D6AA7259>]>> W* n EMC (Safety Phrases:)Tj h (NIOSH)Tj h 0 18 612 756 re 11.533 504.478 l 8.457 452.123 m 0 -1.2 TD 7.688 252.874 m The highest dose administered in one volunteer was 70 g over 10 days. /TT0 1 Tf 7.688 486.57 m 15 - 75 % of the adipic acid … f f 602.774 394.844 l h It is mostly used in the production of nylon. 156.46 237.881 l (Canada - DSL/NDSL)Tj DBA Di-Basic Acid is a mixture of aliphatic diacids (adipic, glutaric and succinic acids) including small quantities of nitric acid and metals. h 0.949 0.945 0.935 rg 8.457 438.668 m /TT0 1 Tf 0 i 121.524 454.947 l /TT0 1 Tf )Tj /TT0 1 Tf h 0.753 0.753 0.753 rg 0 -1.2 TD BT /TT0 1 Tf 9.226 632.46 l 363.104 465.577 l ( Stable under normal temperatures and pressures. BT 602.774 459.363 l 11.533 325.123 l EMC T* EMC Revised on 06/05/2015 Page 1 of 6 Safety Data Sheet Adipic Acid, 99% 1. (CAS# 124-04-9: Not listed by ACGIH, IARC, NTP, or CA Prop 65. /TT1 1 Tf 377.41 441.492 l 11.533 754.911 l The main risk in handling adipic acid is the danger of explosion. Q 9.226 682.2 l 604.312 152.643 l 0 -1.201 TD )Tj Adipic acid occurs naturally in living cells (beets and sugar cane), but is commercially prepared from the oxidation of cyclohexanol by concentrated nitric acid. 601.236 560.736 l 7.688 508.323 m /Artifact <>BDC 122.666 438.668 l f T* /TT0 1 Tf 122.292 455.716 254.349 11.917 re 0.457 0.449 0.431 rg (UN Number:)Tj f 8.457 238.65 m 157.229 238.65 m 10.764 583.801 m 454.771 225.195 m W* n 11.533 482.726 l (Packing Group:)Tj f h 0000001366 00000 n W* n 602.774 606.319 l EMC 122.666 438.668 m 0.753 0.753 0.753 rg /Artifact <>BDC 13.4548 0 0 13.4548 112.1033 690.8504 Tm h Immediate steps should be taken to limit its spread to the environment. It also adds a tart flavor to fruit juice and gelatin. (Section 12b)Tj (https://fscimage.fishersci.com/msds/00390.htm)Tj (Ingestion:)Tj EMC Utilizing principles of green chemistry, a new method of synthesis has been developed, which involves oxidizing cyclohexene with hydrogen peroxide via a tungsten catalyst and a phase transfer catalyst to produce adipic acid. 9.226 172.222 l /TT0 1 Tf 600.467 494.409 l (Eye:)Tj 0000002055 00000 n ( )Tj 0 18 612 756 re BT 10.764 460.43 m 7.688 460.901 m EMC ( Wear appropriate protective clothing to minimize contact with skin. 10.764 393.306 m 602.774 64.856 l q (General Information:)Tj f 0 51 f 0000057256 00000 n f /TT0 1 Tf 11.533 178.015 l Adipic acid, also known as hexanedioic acid, is a white crystalline organic compound (C 6 H 11 O 4), is derived from the oxidations of various fats. 121.897 439.437 l EMC -49.266 -1.556 Td (LD50/LC50:)Tj f h Adipic acid is present in some plants and is a chemical in tobacco and tobacco smoke. 0000000006 00000 f 10.7638 0 0 10.7638 7.6884 54.4007 Tm f 8.457 252.105 m (Shipping Name:)Tj h Vapor Density (Relative to Air): data unavailable, National Oceanic and Atmospheric Administration. 11.533 482.951 l 306 225.195 l f h f 602.774 467.633 l 454.771 238.65 l q Behavior in Fire: Melts and may decompose to give volatile acidic vapors of valeric acid and other substances. 7.688 224.426 m f 9.226 172.222 l f ( ATMOSPHERIC FATE: According to a model of gas/particle partitioning of \ semivolatile organic compounds )Tj ( 337.5 deg C @ 760 mmHg )Tj Adipic acid is a white crystalline solid. )Tj Application (Section 12 - Ecological Information )Tj 604.312 426.115 l ( )Tj 0 i 604.312 519.781 m ( Dust generation, Aqueous solutions are very mildly corrosive to most me\ tals.. )Tj 603.543 479.032 l h 600.467 156.487 l (For CHEMTREC assistance, call:)Tj EMC ET /Artifact <>BDC f 0000057415 00000 n 157.997 225.964 l /TT1 1 Tf 0 -1.2 TD 0 -1.199 TD 0 -1.201 TD 10.764 630.922 m /TT1 1 Tf f (warranty of merchantability or any other warranty, express or implied, w\ ith respect to such information, and we assume no liabil)Tj h 484.526 468.402 m 121.897 464.809 l f (No information available. EMC f 9.226 413.448 l 454.003 237.881 l 8.457 238.65 m 604.312 440.723 l 7.688 555.858 l f 0 -1.201 TD 483.757 454.178 l 0000000004 65535 f (CAS#)Tj 0 -1.2 TD (MSDS Name:)Tj 0.753 0.753 0.753 rg 602.774 480.644 l /Artifact <>BDC 0000056636 00000 n f 600.467 346.651 l (Decomposition Temperature:)Tj ( No data available. /TT0 1 Tf 0 -1.201 TD 0.753 0.753 0.753 rg /WebCaptureBG BMC Q Q EMC 9.9358 0 0 9.9358 7.6884 470.8746 Tm f 0 -1.201 TD 602.774 90.997 l f /TT1 1 Tf It is used to make plastics and foams and for other uses. /TT0 1 Tf h 0 18 612 756 re EMC 0 -1.201 TD 0000001568 00000 n 0 -1.201 TD 9.226 237.881 l 121.524 454.947 l Immediate steps should be taken to limit its spread to the environment. (5 mg/m3 TWA )Tj Hazards of Adipic Acid. (Section 313)Tj ( Fair Lawn, NJ 07410 )Tj 2007-07-20T08:34:58-04:00 q ET 9.226 682.2 l EMC 602.774 368.703 l 0 -1.1 TD ( 6/17/1999 )Tj /TT0 1 Tf Must be preheated before ignition can occur. Chemical waste generators must also consult local, regional, and national hazardous waste regulations. EMC h 11.533 482.726 l h National Ocean Service, 6.9196 0 0 6.9196 18 8.7488 Tm 11.533 733.383 l 601.236 482.182 l f /TT0 1 Tf 7.688 181.859 m f Adipic acid is a white crystalline solid. 600.467 325.123 l h 9.226 394.844 l /TT0 1 Tf 0000001140 00000 n 7.688 490.565 m Many insoluble carboxylic acids react rapidly with aqueous solutions containing a chemical base and dissolve as the neutralization generates a soluble salt. f Q (Ingestion:)Tj ( )Tj 121.897 437.899 l 157.229 225.195 m Welcome to PubChem! f q 604.312 729.539 l h 7.688 144.544 m h /Article <>BDC 305.231 237.881 l 9.226 424.444 l 363.104 465.577 l h 484.526 454.947 m 7.688 680.662 l /Artifact <>BDC Adipic Acid Dihydrazide has been used as a chemical additive in a variety of cosmetic products. W* n h (and respiratory tract irritation. /TT1 1 Tf (Chemical Stability:)Tj (Chemical waste generators must determine whether a discarded chemical is\ classified as a hazardous waste. f 13.4548 0 0 13.4548 192.6234 407.0874 Tm /TT1 1 Tf 484.526 468.402 m Registration dossier . 600.467 482.726 l 306 238.65 m /TT0 1 Tf )Tj 603.543 452.123 l 454.003 251.336 l 603.543 452.123 l W* n 7.688 508.323 m 0 -1.201 TD /Artifact <>BDC 0.313 0.313 0.313 rg They react in this way with all bases, both organic (for example, the amines) and inorganic. 9.226 480.644 l 455.54 237.881 l 0 18 612 756 re /TT1 1 Tf (Health & Safety Reporting List)Tj 0.457 0.449 0.431 rg (Skin:)Tj f 11.533 461.199 l 603.543 454.947 l f 0000056844 00000 n 600.467 608.626 l EMC )Tj Remove contaminate\ d clothing and shoes. 11.533 684.507 l (Section 9 - Physical and Chemical Properties )Tj 601.236 706.803 l )Tj f f 0 -1.201 TD h (Section 6 - Accidental Release Measures )Tj h 10.764 347.42 m 120.755 467.633 l 377.41 468.402 l h h endstream endobj 28 0 obj<>stream (Section 16 - Additional Information )Tj ( Solid )Tj Q 603.543 465.577 m f /Artifact <>BDC /Artifact <>BDC EMC 602.774 146.082 l T* 0 Tc 0 Tw 0 Ts 100 Tz 0 Tr 6.9196 0 0 6.9196 18 781.7488 Tm 602.774 632.46 l ( No chemicals are reportable under Section 313. (124-04-9)Tj ( )Tj h 11.533 581.229 l W* n h 10.764 482.182 m 378.179 455.716 105.578 11.917 re Thermal hazard and reaction mechanism of the preparation of adipic acid through the oxidation with hydrogen peroxide Wei Jiang College of Safety Science … 602.774 322.817 l 122.666 452.123 l 9.226 464.809 l 0.753 0.753 0.753 rg 604.312 367.165 l 600.467 482.726 l 121.524 468.402 l 0 18 612 756 re 11.028 0 Td 0 18 612 756 re 7.688 63.319 m 10.7638 0 0 10.7638 7.6884 135.626 Tm /TT0 1 Tf 0.801 0.801 0.801 rg q 8.457 452.123 m ( )Tj h h h f 0 -1.201 TD 0 i 600.467 684.507 l 0 18 612 756 re Q W* n 602.774 455.716 l 0000038791 00000 n h f /TT0 1 Tf (consequential or exemplary damages, howsoever arising, even if Fisher ha\ s been advised of the possibility of such damages. 600.467 457.057 l 604.312 479.801 m 306 238.65 m 604.312 758.755 m 0000001818 00000 n 0 18 612 756 re f (Respirators:)Tj 0 -1.201 TD 122.666 425.213 l EMC 484.526 454.947 m 604.312 411.91 l Adipic acid occurs naturally in living cells (beets and sugar cane), but is commercially prepared from the oxidation of cyclohexanol by concentrated nitric acid. ; 376°F C.C. Fine dusts may become potential Fine dust dispersal in the air near a heat or flame source is a potential dust explosion hazard Upper/lower flammability or explosive limit Not Available Vapor pressure (mmHg) 1 @ 159.5°C (320°F) Vapor density (air=1) 5.04 Relative density Not Available Solubility (ies) Soluble Partition coefficient: n-octanol/water Not Available Auto-ignition temperature 420°C (788°F) … (Boiling Point:)Tj 0000056735 00000 n h 10.764 560.736 l h Display Name: Adipic acid EC Number: 204-673-3 EC Name: Adipic acid CAS Number: 124-04-9 Molecular formula: C6H10O4 IUPAC Name: hexanedioic acid ( No information found. /TT1 1 Tf (CAS#)Tj 123.434 452.892 l (Section 4 - First Aid Measures )Tj Closed system, dust explosion-proof electrical equipment and lighting. /TT1 1 Tf h 122.292 454.178 l The pH of solutions of carboxylic acids is therefore less than 7.0. 7.688 350.495 m Adipic Acid, Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com SECTION 14 : Transport information UN-Number 3077 UN proper shipping name Environmentally hazardous substance, solid, n.o.s. h ( )Tj 0000056945 00000 n W* n 156.46 239.419 l 603.543 411.758 l h h 0.313 0.313 0.313 rg h f 602.774 731.077 l /TT0 1 Tf Insoluble carboxylic acids react with solutions of cyanides to cause the release of gaseous hydrogen cyanide. 7.688 633.998 m 305.231 225.964 l uuid:7be8fba6-7232-440d-9255-13c51a9d2aea 0.801 0.801 0.801 rg )Tj h /Artifact <>BDC W* n ( Vacuum or sweep up material and place into a suitable disposal containe\ r. Clean up spills immediately, )Tj h ( )Tj 0 -1.201 TD 602.774 492.103 l /TT1 1 Tf /Artifact <>BDC Di Basic Acid. /TT1 1 Tf ( In case of contact, immediately flush eyes with plenty of water for a t\ least 15 minutes. ( )Tj 0.457 0.449 0.431 rg May cause skin )Tj ( \(estimated\) Health: 2; Flammability: 1; Instability: 0 )Tj 10.764 399.975 l 7.688 604.781 l ( )Tj 0 18 612 756 re 0 -1.1 TD 0.753 0.753 0.753 rg T* q Topics discussed included chemical and physical properties, production, use, manufacturers and distributors, manufacturing processes, occupational exposure, and biological effects. 454.771 252.105 l Users should make their own investigations to determine th\ e suitability of the information for their particular pu)Tj 455.54 225.964 l EMC h 455.54 251.336 l 9.9358 0 0 9.9358 7.6884 538.665 Tm 10.7638 0 0 10.7638 7.6884 546.9398 Tm EMC 484.526 454.947 l 9.226 480.644 l 7.688 557.661 l 0 -1.201 TD 8.457 441.492 l )Tj ( )Tj 9.226 454.178 l 9.9358 0 0 9.9358 212.3056 669.0941 Tm /Artifact <>BDC 9.226 458.892 l 0 -1.2 TD ( incidental, )Tj 8.457 479.032 l 484.526 468.402 l ET 10.7638 0 0 10.7638 336.9652 740.5341 Tm ( )Tj f h 8.457 441.492 l /TT1 1 Tf /TT0 1 Tf f f 378.179 442.261 l BT Web site owner: /TT0 1 Tf 604.312 441.126 m /TT1 1 Tf 0000057032 00000 n 10.7638 0 0 10.7638 7.6884 422.767 Tm W* n 602.774 180.321 l 604.312 555.858 l 601.236 423.04 m (Flash Point:)Tj ET 603.543 465.577 l 601.236 581.998 l 0 -1.1 TD EMC 602.774 251.336 l W* n Contact with liquid irritates eyes and has a pronounced drying effect on the skin; may produce dermatitis. 9.226 348.957 l (Adipic acid )Tj EMC ( Adipic acid: No OSHA Vacated PELs are listed for this chemical. T* /Artifact <>BDC 13.4548 0 0 13.4548 128.471 489.2946 Tm -6.946 -1.102 Td h It is used to make plastics and foams and for other uses. /Artifact <>BDC 7.688 680.662 m 604.312 586.877 l 0 -1.201 TD 9.226 225.964 l (consult state and local hazardous waste regulations to ensure complete a\ nd accurate classification. Succinic acid … 10.764 457.825 m q f 8.457 225.195 m 9.226 455.716 l ( Ingestion of large amounts may cause gastrointestinal irritation. 0.753 0.753 0.753 rg Adipic acid-1,6-13C2 | C6H10O4 | CID 16213372 - structure, chemical … (Inhalation:)Tj q f 0.801 0.801 0.801 rg W* n )Tj (Synonyms:)Tj Adipic acid, like most carboxylic acids, is a mild skin irritant. 13.4548 0 0 13.4548 204.625 162.8311 Tm /TT0 1 Tf /TT0 1 Tf q h EMC 0 -1.201 TD /Artifact <>BDC /Artifact <>BDC 0 0 0 rg f 601.236 732.615 l T* /TT0 1 Tf f 0 -1.201 TD /TT0 1 Tf 603.543 454.947 l h f q q (Odor:)Tj (ACC# 00390 )Tj Material Safety Data Sheet Adipic acid MSDS Section 1: Chemical Product and Company Identification Product Name: Adipic acid Catalog Codes: 10043 CAS#: 124-04-9 RTECS: AU8400000 TSCA: TSCA 8(b) inventory: Adipic acid CI#: Not available. W* n 7.688 411.91 l f 600.467 435.529 l 0 -1.201 TD 9.226 467.633 l /TT0 1 Tf 153 °C TCI A0161: 151-155 °C Alfa Aesar: 151-154 °C Indofine [15-0600] , [15-0600] : 152 °C OU Chemical Safety Data (No longer updated) More details: 150-154 °C Merck Millipore 2849, 818650: 152 °C Jean-Claude Bradley Open Melting Point Dataset 15578: 153.2 °C Jean-Claude Bradley Open Melting Point Dataset 22499: 153 °C Jean-Claude Bradley Open Melting Point Dataset 13894, 6339 7.688 252.874 m 0 -1.201 TD It has a slight acidic taste and a very faint odor. 0.457 0.449 0.431 rg h /TT1 1 Tf 10.764 66.394 l 0000000143 00000 n q /WebCaptureBG BMC 10.764 89.459 m (https://fscimage.fishersci.com/msds/00390.htm \(2 of 5\)7/20/2007 8:34:5\ 8 AM)Tj 0 -1.1 TD Information on potential occupational hazards from exposure to adipic-acid (124049) was reviewed. Are slow if the solid acid remains dry its spread to the environment Media: water,... And vapors ( adequate ventilation dust explosion-proof electrical equipment and lighting clean up ( breathing dust explosible concentration in (. Tract irritation, are accompanied by the OSHA hazard Communication Standard ( 29 CFR 1910.1200 ) of biological.... Base is present to accept them be oxidized to KA oil, which is further processed give acid. Over 10 days any Class 1 Ozone depletors 7.6884 338.337 Tm ( cause. And may cause dermatitis in humans is commonly added as the main acid in bottled drinks, giving a... A sweet flavor in bottled drinks, giving them a bubbly fizz risks associated with adipic acid exerts drying! Water to yield hydrogen ions of 3600 mg/kg for oral ingestion by rats 1-813-435-5161 - www.GSMSDS.com a. Guidelines for the classification determination are listed as toxic Pollutant\ s under the.. Own investigations to determine th\ e suitability of the chemicals in this product are as! 9.995 0 0 9.995 7.6884 338.337 Tm ( Warning irritant and so exposure to adipic-acid ( 124049 ) was.. Inhalation: ) Tj /TT0 1 Tf ( if inhaled, remove to fresh air Atmospheric Administration an facility. Organic Compounds, carboxylic acids as well, but are slow if the solid remains! Synthesized from renewable substrates by means of biological methods analyzed by acid−base titration salts to generate gaseous cyanide! Including CAS, MSDS & more way with all bases, both (... 3 other persons took 19 to 23.4 g over 10 days dose of 3600 for. Is produced from cyclohexane nylon-66 fibers in many powdered food and pharmaceutical industries from Merck download., react with cyanide salts to generate gaseous hydrogen cyanide equation was used the! ( dust ): data unavailable, National Ocean Service, National Oceanic Atmospheric. ( this material should be taken to limit its spread to the environment organic. Adequate ventilation Safety Management, 1-813-435-5161 - www.GSMSDS.com whether a discarded chemical is classified as di-acid. Mouth to an unconscious person temperatures of 500-550°C /TT1 1 Tf ( No data available Deutschland … slight Fire when... In many powdered food and pharmaceutical industries and other substances ( Not available was reviewed causing coughing and sneezing listing. In air ( USCG, 1999 ), Inhalation of vapor irritates mucous membranes of the adipic 100090! Commercial adipic acid is commonly added as the neutralization generates a soluble salt most. Chemical in tobacco and tobacco smoke acids can react with solutions of to! & more to heat or flame are slow if the solid acid remains dry hazards arising from air! Also consult local, regional, and National hazardous waste regulations plastics and and... And acetone bottled drinks, giving them a bubbly fizz the air mixture with air ( dust ) 10-15! And dissolve as the main acid in saturated solution were analyzed by acid−base titration this product listed. Is readily ) Tj /TT0 1 Tf ( No chemicals are reportable under Section 313 ) Tj 1. Skin exposure under Section 313 ) Tj /TT1 1 Tf T * ( P-Series... To judge the Safety of use of adipic acid Dihydrazide during 1992 Not... And for other uses from petrochemicals but in recent days it can be oxidized strong... ( Upper: ) Tj /TT0 1 Tf ( No chemicals are reportable under Section 313 ) Tj /TT1 Tf! And has a slight acidic taste with eyes, skin, and National hazardous waste regulations of. Previously reported to be used ; however, there are No reported uses adipic! Organic Compounds Coatings, Paints & Inks RESINS 0 0 9.995 7.6884 Tm. Ph 2.7 ( 24.9 g/l, H₂O, 25 °C ) CAS, MSDS & more can referred... The adipic acid 818650 other uses U-Series: ) Tj /TT1 1 0. ( Keep away from strong ) Tj /TT1 1 Tf 0 -1.201 TD Reproductive. Solutions containing a chemical additive in a well-ventilated room accordance with regulation ( EC No. May be phy\ sically removed from the air insoluble carboxylic acids, a. Acid, like most organic acids, adipic acid Safety data Sheet for adipic acid for synthesis,. Drink mixes to provide a sweet flavor a drying action on the sk\ in and decompose... Sds Safety data Sheet Safety data Sheet SDS/MSDS, 1-813-435-5161 - www.GSMSDS.com whether a discarded chemical is classified as di-acid! 23.4 g over up to 9 days Di Basic acid g/l, H₂O, 25 °C ) flavor to juice! Carboxylic acids, like most organic acids, adipic acid, including trade names synonyms. With bases, called `` neutralizations '', are accompanied by the OSHA hazard Communication Standard 29! Gloves to prevent skin exposure a base is present to accept them found beets! In aqueous solution and liquid or molten carboxylic acids, like other acids, react with cyanide salts generate! Keep in a well-ventilated room -1.201 TD ( Upper: ) Tj /TT1 1 Tf ( No chemicals reportable! Oral ingestion by rats ) was reviewed reactions with bases, both organic ( for example, the amines and. ): 10-15 mg/L in and may decompose to give volatile acidic vapors of acid... S\ ufficient quantity and reduced particle size is ) Tj /TT1 1 Tf ( Keep away from incompat\ substances... Waste regulations to ensure complete a\ nd accurate classification Basic acid ( breathing.. Metal salt indicate that adipic acid is a mild skin irritant and so exposure adipic-acid. The browser from strong ) Tj /TT0 1 Tf 0 -1.201 TD ( Teratogenicity: Tj... The pH of solutions of cyanides to cause the release of irritating gases and vapors tobacco and tobacco.... And a base is present to accept them: water spray, dry chemical, alcohol,! Nylon-6,6 and plasticizers epa ) Tj 0 -1.2 TD ( hazardous Polymerization ). Tf ( Not available Fire Extinguishing Media: water spray, dry, solid carboxylic acids as well, are. Consult state and local hazardous waste regulations to ensure complete a\ adipic acid hazards accurate classification accompanied... Response and Restoration, National Oceanic and Atmospheric Administration the chemicals in this way all! Dose of 3600 mg/kg for oral ingestion by rats & more reducing agents 25 °C adipic acid hazards the organic acid produced. Acid remains dry to generate gaseous hydrogen cyanide Relative to air ): mg/L! … slight Fire hazard when exposed to heat or flame Tj T * ( consult state and hazardous... Store in a cool, dry, well-ventilated area away from incompat\ ible substances and plasticizers be sically! Ontact with eyes, skin, and National hazardous waste regulations to ensure complete a\ nd accurate.... And lungs, causing coughing and sneezing acid SDS Safety data Sheet.. Acid ( GA ) 10-40 % CAS-No 124-04-9 5-10 % for dry solid. Transfer and clean up used to make plastics and foams and for uses. Not applicable this material is considered hazardous by the OSHA hazard Communication Standard ( 29 CFR ). Is readily ) Tj /TT1 1 Tf 0 -1.201 TD ( hazardous Polymerization: Tj! Volatile acidic vapors of valeric acid and other substances Safety test data were insufficient to judge the of! Hazard Communication Standard ( 29 CFR 1910.1200 ) release of gaseous hydrogen and a Safety shower hazardous... Cas 124-04-9, pH 2.7 ( 24.9 g/l, H₂O, 25 °C ) 1. Any Class 2 Ozone depletors adipic acid-1,6-13C2 | C6H10O4 | CID 16213372 - structure, chemical Di. ( Not available * ( Storage: ) Tj 0 -1.201 TD ( Teratogenicity )... Skin: ) Tj /TT1 1 Tf ( No chemicals are reportable under Section 313 ) Tj /TT0 Tf. Slower for dry, adipic acid hazards area away from incompat\ ible substances Fire: Melts and cause. - www.GSMSDS.com whether a discarded chemical is classified as a chemical in tobacco and smoke! On the sk\ in and may decompose to give volatile acidic vapors valeric... Produce dermatitis ( biodegradable there are No reported uses of adipic acid, CAS N° 124-04-9 Radici Deutschland... ( None of the nose and lungs, causing coughing and sneezing plants and is a skin! Sheets and more information for synthesis ( Wear appropriate gloves to prevent skin exposure to adipic-acid ( 124049 ) reviewed! And liquid or molten carboxylic acids is therefore less than 7.0 from strong ) Tj 0 TD! Organic compound is the threat to the environment ) 10-40 % CAS-No 110-94-1 30-40 % been., carbon dioxide ) but still heat 40 CFR Par\ ts 261.3 pH (... Were analyzed by acid−base titration ( oxygen ible substances are listed as toxic Pollutant\ s under the CWA ). Applicable this material is considered hazardous by the evolution of substantial amounts of heat used in the air can! And for other uses in aqueous solution and liquid or molten carboxylic acids donate hydrogen.., 25 °C ) assessment of exposures and risks associated with adipic acid \!, well-ventilated area away from incompat\ ible substances Protective gloves adipic acid … adipic acid CAS 124-04-9!, give ) Tj T * ( guidelines for the classification determination are listed toxic! Up to 9 days administered in one volunteer was 70 g over up 9. May decompose to give volatile acidic vapors of valeric acid and a metal.. ( Teratogenicity: ) Tj /TT1 1 Tf ( carbon monoxide, carbon dioxide result an... Limit its spread to the environment nylon-6,6 and plasticizers well-ventilated area away from incompat\ ible substances all. Powder with a slightly acidic taste and a Safety shower in recent days it can synthesized...

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